N-(4-Methylphenyl)-2-nitrobenzenesulfonamide
نویسندگان
چکیده
In the crystal of the title compound, C(13)H(12)N(2)O(4)S, the conformation of the N-H bond in the -SO(2)-NH- segment is syn to the ortho-nitro group in the sulfonyl benzene ring. The mol-ecule is twisted at the S-N bond with a torsion angle of 76.55 (18)°. The dihedral angle between the planes of the rings is 72.64 (8)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O(S) hydrogen bonds to form inversion dimers.
منابع مشابه
N-(2-Methylphenyl)-4-nitrobenzenesulfonamide
In the title compound, C(13)H(12)N(2)O(4)S, the dihedral angle between the planes of the rings is 51.11 (10)°. In the crystal, mol-ecules are linked into inversion dimers through pairs of N-H⋯O(S) hydrogen bonds.
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In the title compound, C(13)H(12)N(2)O(4)S, the dihedral angle between the benzene rings is 73.64 (7)°. The amide H atom exhibits bifurcated hydrogen bonding: an intra-molecular N-H⋯O hydrogen bond generates an S(7) motif while in the crystal, N-H⋯O(S) hydrogen bonds link the mol-ecules into zigzag C(4) chains running along the b axis.
متن کاملN-(2-Methylphenyl)-2-nitrobenzenesulfonamide
In the title compound, C(13)H(12)N(2)O(4)S, the dihedral angle between the benzene rings is 53.44 (14)°. The amide H atom exhibits bifurcated hydrogen bonding: an intra-molecular N-H⋯O hydrogen bond generates an S(7) motif while in the crystal, N-H⋯O(S) hydrogen bonds link the mol-ecules into zigzag C(4) chains along the c axis.
متن کاملN-(4-Chlorophenyl)-4-nitrobenzenesulfonamide
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متن کاملN-(4-Chlorophenyl)-2-nitrobenzenesulfonamide
In the title compound, C(12)H(9)ClN(2)O(4)S, the dihedral angle between the aromatic rings is 70.27 (8)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O(S) hydrogen bonds, forming inversion dimers.
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